Product ID:P2271, PYRROLIDINE
MSDS Date:06/17/1994
FSC:6810
NIIN:00N054799
MSDS Number: BVYSX

Emergency Phone: 314-771-5765

Info Phone: 314-771-5765

Cage: 21076

Telephone: 314-771-5765

Cage: 21076

PYRROLIDINE

CAS: 123-75-1

RTECS: UX9650000

OSHA PEL N/K

ACGIH TLV: N/K

LD50 LC50 Mixture:LD50: (ORAL, RAT) 300 MG/KG
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE: HARMFUL IF SWALLOWED, INHALED
OR ABSORBED THROUGH SKIN. MATERIAL IS EXTREMELY DESTRUCTIVE TO
TISSUE OF THE MUCOUS MEMBRANES & UPPER RESPIRATORY TRACT, EYES AND
SKIN. INHALATION MAY BE FATAL AS A RESULT OF SPASM, INFLAMMATION &
EDEMAOF THE LARYNX & BRONCHI, CHEMICAL PNEUMONITIS & PULMONARY
(EFTS OF OVEREXO)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ: EDEMA. PROLONGED CONTACT CAN CAUSE:
SEVERE IRRITATION OR BURNS. TO THE BEST OF MANUFACTURER'S
KNOWLEDGE, THE CHEMICAL, PHYSICAL & TOXICOLOGICAL PROPERTIES HAVE
NOT BEEN THOROUGHLY INVESTIGAT ED.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

First Aid:EYES/SKIN: IMMEDIATELY FLUSH SKIN W/COPIOUS AMOUNTS OF WATER
FOR AT LEAST 15 MIN WHILE REMOVING CONTAMD CLTHG & SHOES. ASSURE
ADEQUATE FLUSHING OF EYES BY SEPARATING EYELIDS W/FINGERS. INHAL:
REMOVE T O FRESH AIR. IF NOT BREATHING GIVE ARTIFICIAL RESPIRATION.
IF BREATHING IS DFCLT, GIVE OXYGEN. INGEST: WASH OUT MOUTH W/WATER
PROVIDED PERSON IS CONSCIOUS. CALL MD. WASH CONTAMD CLTHG BEFORE
REUSE.

Flash Point:37.0F,2.8C
Lower Limits:1.6%
Upper Limits:10.6%
Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL POWDER OR APPROPRIATE
FOAM. WATER MAY BE EFTIVE FOR COOLING BUT MAY NOT EFT
EXTINGUISHMENT.
Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA AND FULL
PROTECTIVE EQUIPMENT . FLAMMABLE.
Unusual Fire/Explosion Hazard:VAP MAY TRAVEL CONSIDERABLE DIST TO
SOURCE OF IGNIT & FLASH BACK. CNTNR EXPLOS MAY OCCUR UNDER FIRE
CNDTNS. EMITS TOX FUMES UNDER FIRE CNDTNS. FORMS (SUPDAT)

Spill Release Procedures:EVACUATE AREA. SHUT OFF ALL SOURCES OF IGNIT.
WEAR NIOSH/MSHA APPRVD SCBA, RUB BOOTS & HEAVY RUB GLOVES. COVER W/
DRY-LIME, SAND/SODA ASH. PLACE IN COVERED CNTNRS USING NON-SPARKING
TOOLS & TRANSPORT OUTDOORS. VENT AREA & WASH SPILL SITE (SUPDAT)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:KEEP TIGHTLY CLOSED. KEEP AWAY FROM
HEAT, SPARKS AND OPEN FLAME. HANDLE AND STORE UNDER NITROGEN. STORE
IN A COOL, DRY PLACE. NO SMOKING.
Other Precautions:DO NOT BREATHE VAPOR. AVOID CONTACT WITH EYES, SKIN &
CLOTHING. AVOID PROLONGED OR REPEATED EXPOSURE. CORROSIVE. TOXIC.
LACHRYMATOR. FLAMMABLE.

Respiratory Protection:WEAR APPROPRIATE NIOSH/MSHA APPROVED RESPIRATOR.
Ventilation:USE ONLY IN A CHEMICAL FUME HOOD.
Protective Gloves:CHEMICAL-RESISTANT GLOVES.
Eye Protection:ANSI APPRVD CHEM WORKERS GOGGS (SUPDAT)
Other Protective Equipment:WEAR APPROPRIATE PROTECTIVE CLOTHING. EMERG
EYE WASH AND DELUGE SHOWER WHICH MEETS ANSI DESIGN CRITERIA .
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
VP: 49 @ 20C; 128 @ 39C. EXPLO HAZ: EXPLO MIXTURES IN AIR. SPILL PROC:
AFTER MATL PICKUP IS COMPLETE. EYE PROT: & FULL LENGTH FACESHIELD .

HCC:F5
Boiling Pt:B.P. Text:>189F,>87C
Vapor Pres:SUPDAT
Vapor Density:2.45
Spec Gravity:0.852
Appearance and Odor:COLORLESS LIQUID.

Stability Indicator/Materials to Avoid:YES
ACIDS, ACID CHLORIDES, ACID ANHYDRIDES, STRONG OXIDIZING AGENTS, CARBON
DIOXIDE.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:THERMAL DECOMPOSITION MAY PRODUCE
CARBON MONOXIDE, CARBON DIOXIDE AND NITROGEN OXIDES.

Waste Disposal Methods:BURN IN A CHEMICAL INCINERATOR EQUIPPED WITH AN
AFTERBURNER AND SCRUBBER BUT EXERT EXTRA CARE IN IGNITING AS THIS
MATERIAL IS HIGHLY FLAMMABLE. OBSERVE ALL FEDERAL, STATE AND LOCAL
ENVIRONMENTAL REGUL ATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.